Cyclopentadienyl-bis(oxazoline) Magnesium and Zirconium Complexes in Aminoalkene Hydroaminations
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منابع مشابه
Cyclopentadienyl-bis(oxazoline) Magnesium and Zirconium Complexes in Aminoalkene Hydroaminations
A new class of cyclopentadiene-bis(oxazoline) compounds and their piano-stool-type organometallic complexes have been prepared as catalysts for hydroamination of aminoalkenes. The two compounds MeC(Ox)2C5H5 (BoCpH; Ox = 4,4-dimethyl-2-oxazoline) and MeC(Ox)2C5Me4H (Bo CpH) are synthesized from C5R4HI (R = H, Me) and MeC(Ox)2Li. These cyclopentadienebis(oxazolines) are converted into ligands tha...
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متن کاملSynthesis of lithium corrole and its use as a reagent for the preparation of cyclopentadienyl zirconium and titanium corrole complexes.
The lithium corrole complex (Mes(2)(p-OMePh)corrole)Li(3)·6THF (1·6THF), prepared via deprotonation of the free-base corrole with lithium amide, acts as precursor for the preparation of cyclopentadienyl zirconium(iv) corrole (2) and pentamethylcyclopentadienyl titanium(IV) corrole (3).
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ژورنال
عنوان ژورنال: Organometallics
سال: 2015
ISSN: 0276-7333,1520-6041
DOI: 10.1021/acs.organomet.5b00771